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Electron arrangement notes and lesson for GCSE chemistry (free PDF download)

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Electron arrangement notes and lesson for GCSE chemistry (free PDF download)

This chemistry grades 9-10 lesson on electron arrangement notes gives the key ideas first, then worked examples and diagrams. After that, practise with the worksheet on electron arrangement and check yourself with the quiz.

Quick answer: Electrons fill shells from the nucleus outwards, holding 2, 8 and 8 in the first three shells of the first 20 elements. Also, the number of outer electrons gives the group, and the number of shells gives the period. Mendeleev ordered the elements by mass and left gaps, and Moseley fixed the order by atomic number.

Level: Chemistry grades 9-10 (GCSE · IGCSE · O Level · Class 9-10) · Curriculum: HS-PS1-1, HS-PS1-2

Electron arrangement notes: the key ideas

How are electrons arranged in shells?

Electrons sit in shells (also called energy levels) around the nucleus. Each shell can hold only a limited number of electrons, and the lowest shell fills first.

Definition

The electron arrangement of an atom lists the number of electrons in each shell, starting from the one nearest the nucleus, for example 2,8,5.

Key rule

For the first 20 elements: shell 1 holds up to 2 electrons, shell 2 holds up to 8, shell 3 holds up to 8. Fill each shell before starting the next.

Electron shell diagrams of sodium 2,8,1, chlorine 2,8,7 and argon 2,8,8NaClArsodium 2,8,1chlorine 2,8,7argon 2,8,8Fill the lowest shell first: 2, then 8, then 8 (first 20 elements)
Three period 3 atoms: sodium (2,8,1), chlorine (2,8,7) and argon (2,8,8).

The third period shows the pattern clearly. In addition, each step to the right adds one proton and one electron.

ElementAtomic numberElectron arrangementOuter electrons
Sodium112,8,11
Magnesium122,8,22
Aluminium132,8,33
Silicon142,8,44
Phosphorus152,8,55
Sulfur162,8,66
Chlorine172,8,77
Argon182,8,88
Worked example 1

Moreover, write the electron arrangement of phosphorus (atomic number 15). Also, a neutral atom has 15 electrons. Shell 1 takes 2, leaving 13. Then shell 2 takes 8, leaving 5. Shell 3 takes the last 5. Answer: 2,8,5.

How does electron arrangement explain the periodic table?

In addition, the periodic table lists elements in order of atomic number. Rows are periods and columns are groups. Moreover, the arrangement of electrons tells you exactly where an element belongs.

Key rule

Also, the group number equals the number of electrons in the outer shell. In addition, the period number equals the number of occupied shells. Noble gases (Group 0) have a full outer shell.

Simplified periodic table of periods 1 to 4 with groups 1 to 7 and 0, coloured by metals, metalloids and non-metals12345670Group1234PeriodHHeLiBeBCNOFNeNaMgAlSiPSClArKCaGaGeAsSeBrKrtransition metalsmetalmetalloidnon-metal
Periods run across, groups run down. Metals sit on the left, non-metals on the right.
Worked example 2

Moreover, an atom has the arrangement 2,8,8,2. It has 2 + 8 + 8 + 2 = 20 electrons, so its atomic number is 20 (calcium). So it has 4 shells, so it is in period 4. It has 2 outer electrons, so it is in Group 2. Answer: calcium, Group 2, period 4.

Common mistake

Also, do not mix up periods and groups. Sodium (2,8,1) is in Group 1 because of its 1 outer electron, but it is in period 3 because it has 3 shells. Helium has only 2 electrons, yet it is in Group 0 because its single shell is full.

Elements in one group have the same number of outer electrons, so they react in similar ways. Lithium, sodium and potassium each have one outer electron and all are soft, reactive metals. Metals are on the left and in the middle and tend to lose outer electrons. Non-metals are on the right and tend to gain or share them.

Who developed the periodic table?

Chemists first tried to organise the elements by their relative atomic mass. Johann Döbereiner noticed triads of similar elements. John Newlands saw that every eighth element was similar, but his pattern failed beyond calcium. In 1869 Dmitri Mendeleev made the most useful table. He placed elements in order of mass, started a new row when properties repeated, and left gaps for elements not yet found.

Timeline of ideas for classifying elements: Dobereiner 1829, Newlands 1864, Mendeleev 1869, Moseley 19131829Döbereinertriads of similar elements1864Newlandsoctaves by mass1869Mendeleevgaps and predictions1913Moseleyorder by atomic number
How ideas for sorting the elements developed.

Mendeleev predicted the properties of a missing element below silicon, which he called eka-silicon. Germanium, discovered in 1886, matched his predictions closely.

PropertyMendeleev’s predictionGermanium (measured)
Relative atomic mass7272.6
Density5.5 g/cm³5.32 g/cm³
Formula of oxideXO₂GeO₂
Formula of chlorideXCl₄GeCl₄

Mendeleev also swapped a few elements, such as tellurium and iodine, so that elements with similar properties shared a column. Henry Moseley later showed in 1913 that the true order is by atomic number, which explained why those swaps were right.

Lina’s tip

In addition, read the arrangement from the right: the last number is the group number (for Groups 1 to 7) and the count of numbers is the period. For 2,8,6 the last number is 6 and there are 3 numbers, so Group 6, period 3.

Key points to remember
  • Shells hold 2, 8, 8 electrons (first 20 elements); fill the lowest shell first.
  • Group number = outer electrons; period number = number of shells; Group 0 has a full outer shell.
  • Elements in the same group have the same outer electron number and react in similar ways.
  • Mendeleev (1869) left gaps and predicted germanium; Moseley (1913) ordered by atomic number.
  • Metals are on the left and in the centre and lose electrons; non-metals are on the right.

Shells, groups and the periodic table: frequently asked questions

How do you write an electron arrangement?

Moreover, find the number of electrons, which equals the atomic number of a neutral atom. Put 2 in the first shell, then 8 in the second, then up to 8 in the third, and so on. Also, write the numbers in order, separated by commas, such as 2,8,3.

How do you find the group and period from the electron arrangement?

In addition, the last number is the number of outer electrons, which gives the group. Moreover, the number of shells, meaning how many numbers you wrote, gives the period. Also, the arrangement 2,8,7 means Group 7 and period 3.

Why are noble gases unreactive?

In addition, a full outer shell is a very stable arrangement. Helium has 2 outer electrons and the other noble gases have 8. Their atoms have no tendency to lose, gain or share electrons.

Why did Mendeleev leave gaps in his table?

He believed that elements with similar properties should share a column. Where no known element fitted, he left a space and predicted the missing element. Moreover, the properties of germanium matched his predictions, which convinced chemists.

What did Moseley change about the table?

Moseley showed that the elements should be ordered by atomic number, the number of protons, rather than by relative atomic mass. Also, this explained cases like tellurium and iodine, where mass order gives the wrong column.

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